Transport of Sellafield-derived C-14 from the Irish Sea through the North Channel

Since the early 1950s, the Sellafield nuclear fuel reprocessing plant in Northwest England has released radio-carbon into the Irish Sea in a mainly inorganic form as part of its authorized liquid effluent discharge. In contrast to the trend in which the activities of most radionuclides in the Sellafield liquid effluent have decreased substantially, C-14 discharges have increased since 1994-95. This has largely been due to a policy change favoring marine discharges over atmospheric discharges. C-14 is radiologically important due to its long half life, mobility in the environment, and propensity for entering the food chain. Current models for radionuclide dispersal in the Irish Sea are based on a reversible equilibrium distribution coefficient (k(d)), an approach which has been shown to be inadequate for C-14. Development of predictive models for the fate of Sellafield-derived C-14 requires a thorough understanding of the biogeochemical fluxes between different carbon reservoirs and the processes controlling the net flux of C-14 out of the Irish Sea, through he North Channel. In this study., both an empirical and a halving time approach indicate that close to 100% of the C-14 that is discharged from Sellafield is dispersed beyond the Irish Sea on a time-scale of months in the form of DIC, with little transfer to the PIC, POC, and DOC fractions, indicating that the "dilute and disperse" mechanism is operating satisfactorily. This is consistent with previous research that indicated little transfer of C-14 to Irish Sea sediments, While significant C-14 enhancements have been observed in the biota of the Irish Sea, this observation is not necessarily in conflict with either of the above as the total biomass has to be taken into account in any calculations of C-14 retention within the Irish Sea

Sources of anthropogenic C-14 to the North Sea

The Sellafield nuclear fuel reprocessing plant on the northwest coast of England is the largest source of anthropogenic radiocarbon to the UK coastal environment. In a mid-1990s study of C-14 distribution around the UK coast, the pattern of dilution with increasing distance from Sellafield appeared to be perturbed by anomalously high C-14 activities in marine biota in the coastal environment of northeast England. This present study was undertaken during 1998 and 1999 to determine whether this C-14 enhancement was due to Sellafield or the nuclear power plants on the east coast. Seawater, seaweed (Fucus sp.), and mussel (Mytilus edulis) samples that were collected from the vicinity of the Torness and Hartlepool advanced gas-cooled reactor (AGR) nuclear power stations were all enhanced above the contemporary regional background activity derived from natural production and atmospheric nuclear weapons testing. We used previously published dilution factors and transfer times for Tc-99 between Sellafield and various points on the UK coast to determine likely Sellafield- derived C-14 contributions to the activities at the nuclear power plant sites. The results suggest that the activities observed at Torness, which are only marginally enhanced above the natural background activity, are possibly due to discharges from Sellafield; however, the significant C-14 enhancements at Hartlepool are not Sellafield-derived. Furthermore, since both reactors have the same fundamental design, the low activities at the Torness AGR imply that the activities at Hartlepool are not from the AGR, suggesting that there is an input of C-14 to the marine environment in the vicinity of Hartlepool which is probably non-nuclear-power related. However, there is no other authorized site in the area that could account for the observed C-14 enrichments; therefore, further research is required to ascertain the source of this C-14

Sellafield-derived anthropogenic C-14 in the marine intertidal environment of the NE Irish Sea

The intertidal biota from Parton beach, close to the Sellafield nuclear fuel reprocessing plant, were all found to be enriched in radiocarbon relative to ambient background. The degree of enrichment appears to reflect the positions of the biota in the food chain once the dilution in seaweed from atmospheric uptake is taken into account. Close to the low-water mark, the order was mussels gt limpets gt anemones congruent to winkles gt seaweed. The same order was observed close to the high-water mark, except that anemones were absent from this area. The activities in the biogeochemical fractions of the water column reflect the fact that discharges are primarily in the form of dissolved inorganic carbon (DIC), which is subsequently transferred to the particulate organic carbon (POC) and, to a lesser extent, the dissolved organic carbon (DOC), and finally, the particulate inorganic carbon (PIC). Analysis of intertidal sediment suggests that there is likely to be a gradual increase in the specific activity of C-14 in the inorganic component of this material as Sellafield contaminated organisms die and their shells are ground down by natural processes

Terrigenous sediment-dominated reef platform infilling: an unexpected precursor to reef island formation and a test of the reef platform size-island age model in the Pacific

Low-lying coral reef islands are considered highly vulnerable to climate change, necessitating an improved understanding of when and why they form, and how the timing of formation varies within and among regions. Several testable models have been proposed that explain inter-regional variability as a function of sea-level history and, more recently, a reef platform size model has been proposed from the Maldives (central Indian Ocean) to explain intra-regional (intra-atoll) variability. Here we present chronostratigraphic data from Pipon Island, northern Great Barrier Reef (GBR), enabling us to test the applicability of existing regional island evolution models, and the platform size control hypothesis in a Pacific context. We show that reef platform infilling occurred rapidly (~4–5 mm yr−1) under a “bucket-fill” type scenario. Unusually, this infilling was dominated by terrigenous sedimentation, with platform filling and subsequent reef flat formation complete by ~5000 calibrated years BP (cal BP). Reef flat exposure as sea levels slowly fell post highstand facilitated a shift towards intertidal and subaerial-dominated sedimentation. Our data suggest, however, a lag of ~1500 yr before island initiation (at ~3200 cal BP), i.e. later than that reported from smaller and more evolutionarily mature reef platforms in the region. Our data thus support: (1) the hypothesis that platform size acts to influence the timing of platform filling and subsequent island development at intra-regional scales; and (2) the hypothesis that the low wooded islands of the northern GBR conform to a model of island formation above an elevated reef flat under falling sea levels

Evidence for anthropogenic ¹⁴C-enrichment in estuarine waters adjacent to the North Sea

[1] The isotopic composition (d13C and D14C) of high molecular weight dissolved organic carbon (HMW DOC) was studied in the Tyne and Tweed estuaries, NE England. Despite significant removal of terrigenous HMW DOC in the low salinity regions (S < 15), D14C remained modern with little variation around 115%. This lack of apparent age discrimination was attributed to either non-oxidative removal or the absence of a significant proportion of old refractory C in the HMW DOC pool. At S < 15, we observed seaward increases in d13C and D14C. With no documented local 14C inputs, we attributed non-bomb related 14C-enrichment at S < 15 to a possible ‘lingering effect’ of distal anthropogenic sources in near-coastal North Sea HMW DOC. Given the global distribution of potential sources, we propose that anthropogenic 14C should be considered in assigning ages of DOC pools in near-coastal waters and suggest its possible use as a tracer for DOC transformations

Radiocarbon analysis of methane at the NERC Radiocarbon Facility (East Kilbride)

Methane is the second most important anthropogenically produced greenhouse gas, and radiocarbon (14C) analysis is extremely valuable in identifying its age and source in the environment. At the NERC Radiocarbon Facility (East Kilbride, UK) we have developed expertise in analysis of methane 14C concentration and methodological approaches to field sampling over the past 20 years. This has opened a wide range of applications, which have mainly focused on (1) the age and source of methane emitted by peatlands and organic soils (e.g. to quantify the release of ancient carbon), (2) the source of aquatic emissions of methane, and (3) the age of methane generated by amenity and illegal landfill. Many of these scientifically important applications involve challenging sampling and measurement considerations, which our development program has continually aimed to overcome. Here, we describe our current methods, and recent improvements to aid field collection of samples in remote locations. We present the results of tests which (1) show the effectiveness of our methods to remove contaminants, especially CO2, (2) quantify the 14C background contribution, and (3) demonstrate the reliability of metal gas storage canisters for sample storage

Performance of the rebuilt SUERC single-stage accelerator mass spectrometer

The SUERC bipolar single-stage accelerator mass spectrometer (SSAMS) has been dismantled and rebuilt to accommodate an additional rotatable pre-accelerator electrostatic spherical analyser (ESA) and a second ion source injector. This is for the attachment of an experimental positive-ion electron cyclotron resonance (ECR) ion source in addition to a Cs-sputter source. The ESA significantly suppresses oxygen interference to radiocarbon detection, and remaining measurement interference is now thought to be from 13C injected as 13CH molecule scattering off the plates of a second original pre-detector ESA

Time scales and modes of reef lagoon infilling in the Maldives and controls on the onset of reef island formation

Faro are annular reefs, with reef flats near sea level and lagoons of variable depth, characteristic of both the perimeter and lagoons of Maldivian (Indian Ocean) atolls. Their geomorphic development remains largely unknown, but where faro lagoons (termed velu in Maldivian) have infilled and support reef islands, these provide precious habitable land. Understanding the timing and modes of velu infilling is thus directly relevant to questions about reef island development and vulnerability. Here we use a chronostratigraphic data set obtained from a range of atoll-interior faro with partially to fully filled velu (including those with reef islands) from Baa (South Maalhosmadulu) Atoll, Maldives, to determine time scales and modes of velu infilling, and to identify the temporal and spatial thresholds that control reef island formation. Our data suggest a systematic relationship between faro size, velu infilling, and island development. These relationships likely vary between atolls as a function of atoll lagoon depth, but in Baa Atoll, our data set indicates the following faro-size relationships exist: (1) faros <∼0.5 km2 have velu that were completely infilled by ca. 3000 calibrated years B.P. (cal yr B.P.) with islands having established on these deposits by ca. 2.5 cal kyr B.P.; (2) faros >0.5 km2 but <∼1.25 km2 have velu in late stages of infill, may support unvegetated sand cays and, given sufficient sand supply, may evolve into larger, more permanent islands; and (3) faros >∼1.25 km2 have unfilled (deeper) velu which might only infill over long time scales and which are thus unlikely to support new island initiation. These new observations, when combined with previously published data on Maldivian reef island development, suggest that while the velu of the largest faro are unlikely to fill over the next few centuries (at least), other faro with near-infilled velu may provide important foci for future reef-island building, even under present highstand (and slightly rising) sea levels

Reconstructing paleoseismic deformation, 2: 1000 years of great earthquakes at Chucalén, south central Chile

In this paper we adopt a quantitative biostratigraphic approach to establish a 1000-year-long coastal record of megathrust earthquake and tsunami occurrence in south central Chile. Our investigations focus on a site in the centre of the rupture segment of the largest instrumentally recorded earthquake, the AD 1960 magnitude 9.5 Chile earthquake. At Chucalén coseismic subsidence in 1960 is recorded in the lithostratigraphy and biostratigraphy of coastal marshes, with peat overlain by minerogenic sediment and changes in the assemblages of diatoms (unicellular algae) indicating an abrupt increase in relative sea level. In addition to the 1960 earthquake, the stratigraphy at Chucalén records three earlier earthquakes, the historically documented earthquake of 1575 and two prehistoric earthquakes, radiocarbon dated to AD 1270–1450 and 1070–1220. Laterally extensive sand sheets containing marine or brackish diatom assemblages suggest tsunami deposition associated with at least two of the three pre-1960 earthquakes. The record presented here suggests a longer earthquake recurrence interval, averaging 270 years, than the historical recurrence interval, which averages 128 years. The lack of geologic evidence at Chucalén of two historically documented earthquakes, in 1737 and 1837, supports the previously suggested hypothesis of variability in historical earthquake characteristics. Our estimates of coseismic land-level change for the four earthquakes range from meter-scale subsidence to no subsidence or slight uplift, suggesting earthquakes completing each ∼270 year cycle may not share a common, characteristic slip distribution. The presence of buried soils at elevations below their modern equivalents implies net relative sea-level rise over the course of the Chucalén paleoseismic record, in contrast to relative sea-level fall over preceding millennia inferred from sites on the mainland. Sea-level rise may contribute to the preservation of evidence for multiple earthquakes during the last millennium, while net relative sea-level fall over the last 2000–5000 years may explain the lack of evidence for older earthquakes